Trafalgar D. Law is the captain of the Heart Pirates and he acquired the title of a Shichibukai by sending the World Government the hearts of 100 Pirates. Law became a Shichibukai to take down Doflamingo, who had Corazon. Once he had defeated and taken down Doflamingo, he handed in his resignation and then formed an alliance with Luffy.
Trafalgar D. Water Law, One Piece Wiki
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